| Date | Location | Result | |
| Nov 19, 2021 | Bristol, Tenn. | North Greenville 3, UNC Pembroke 0 (25-18,25-7,25-18) | Box score |
| Nov 16, 2021 | Pembroke, N.C. | UNC Pembroke 3, Erskine 0 (25-14,25-14,25-13) | Box score |
| Nov 10, 2021 | Pembroke, N.C. | Francis Marion 3, UNC Pembroke 1 (25-20,25-22,19-25,25-19) | Box score |
| Nov 06, 2021 | Pembroke, N.C. | UNC Pembroke 3, Lees-McRae 1 (25-17,19-25,25-11,26-24) | Box score |
| Nov 05, 2021 | Pembroke, N.C. | UNC Pembroke 3, King 1 (23-25,25-12,25-16,25-17) | Box score |
| Nov 02, 2021 | Murfreesboro, N.C. | UNC Pembroke 3, Chowan 0 (26-24,25-22,25-15) | Box score |
| Oct 26, 2021 | Newberry, S.C. | Newberry 3, UNC Pembroke 1 (22-25,25-19,25-16,27-25) | Box score |
| Oct 23, 2021 | Pembroke, N.C. | UNC Pembroke 3, Mount Olive 2 (26-24,21-25,25-16,16-25,15-5) | Box score |
| Oct 22, 2021 | Wilson, N.C. | UNC Pembroke 3, Barton 0 (25-15,25-23,25-22) | Box score |
| Oct 15, 2021 | Pembroke, N.C. | UNC Pembroke 3, Converse 0 (25-19,25-14,25-13) | Box score |
| Oct 13, 2021 | Florence, S.C. | Francis Marion 3, UNC Pembroke 2 (28-26,14-25,15-25,25-22,15-10) | Box score |
| Oct 09, 2021 | Pembroke, N.C. | Flagler 3, UNC Pembroke 1 (25-17,25-18,18-25,25-21) | Box score |
| Oct 09, 2021 | Pembroke, N.C. | UNC Pembroke 3, Southern Wesleyan 0 (25-9,25-10,25-16) | Box score |
| Oct 08, 2021 | Pembroke, N.C. | UNC Pembroke 3, Belmont Abbey 0 (25-22,25-20,25-15) | Box score |
| Oct 05, 2021 | Pembroke, N.C. | UNC Pembroke 3, Coker 0 (25-17,25-17,25-17) | Box score |
| Oct 02, 2021 | Due West, S.C. | UNC Pembroke 3, Erskine 1 (23-25,25-19,27-25,25-16) | Box score |
| Oct 01, 2021 | Royston, Ga. | Emmanuel 3, UNC Pembroke 1 (25-20,25-18,23-25,25-20) | Box score |
| Sep 28, 2021 | Pembroke, N.C. | UNC Pembroke 3, Barton 0 (25-14,25-20,25-19) | Box score |
| Sep 25, 2021 | Mount Olive, N.C. | UNC Pembroke 3, Mount Olive 0 (25-23,25-21,29-27) | Box score |
| Sep 24, 2021 | Pembroke, N.C. | UNC Pembroke 3, Chowan 0 (25-19,25-22,25-18) | Box score |
| Sep 22, 2021 | Belmont, N.C. | UNC Pembroke 3, Belmont Abbey 0 (25-15,25-16,25-19) | Box score |
| Sep 17, 2021 | Fayetteville, N.C. | UNC Pembroke 3, Fayetteville St. 1 (23-25,25-14,26-24,25-14) | Box score |
| Sep 16, 2021 | Tigerville, S.C. | UNC Pembroke 3, North Greenville 1 (25-23,25-13,21-25,29-27) | Box score |
| Sep 14, 2021 | Hartsville, S.C. | UNC Pembroke 3, Coker 1 (16-25,25-14,25-23,25-8) | Box score |
| Sep 11, 2021 | Valdosta, Ga. | UNC Pembroke 3, Albany State 0 (25-17,25-21,25-17) | Box score |
| Sep 11, 2021 | Valdosta, Ga. | Valdosta State 3, UNC Pembroke 0 (25-17,25-22,25-17) | Box score |
| Sep 10, 2021 | Valdosta, Ga. | Eckerd 3, UNC Pembroke 0 (26-24,25-22,25-17) | Box score |
| Sep 10, 2021 | Valdosta, Ga. | Saint Leo 3, UNC Pembroke 0 (25-21,25-20,25-23) | Box score |
| Sep 07, 2021 | Pembroke, N.C. | UNC Pembroke 3, Winston-Salem 0 (25-17,25-16,25-15) | Box score |
| Sep 07, 2021 | Pembroke, N.C. | UNC Pembroke 3, Newberry 0 (25-22,25-18,25-21) | Box score |
| Sep 04, 2021 | Aiken, S.C. | Auburn Montgomery 3, UNC Pembroke 1 (26-24,26-24,21-25,25-20) | Box score |
| Sep 04, 2021 | Aiken, S.C. | USC Aiken 3, UNC Pembroke 0 (25-12,25-20,25-19) | Box score |
| Sep 03, 2021 | Aiken, S.C. | UNC Pembroke 3, Carson-Newman 1 (25-18,20-25,25-16,25-14) | Box score |
| Sep 03, 2021 | Aiken, S.C. | UNC Pembroke 3, Lincoln Memorial 0 (25-15,25-16,25-23) | Box score |